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PaintingExam task · CATCHTask page

A painter is repainting a galvanized metal roof and steel gutters on a barn. He wipes them down with a rag, applies an oil-based rust-inhibiting alkyd primer straight from the can, then an alkyd topcoat. Six months later it's peeling off the galvanized sections in sheets but holding on the rusty steel gutters. Why?

Model A

The primer failed because it was applied to unetched, passivated galvanized steel.

Root Cause: New or weathered galvanizing develops a passive zinc carbonate/oxide layer ("white rust") that repels oil-based alkyds. Alkyd resins saponify (turn to soap) on contact with alkaline zinc surfaces, destroying adhesion. The rusty gutters worked because iron oxide provides mechanical tooth and chemical compatibility for alkyds.

Code/Standard References:

  • SSPC-SP 16 / ASTM D6386: Requires chemical etching or mechanical profiling of galvanizing before alkyd application.
  • ASTM D520: Zinc dust primers (inorganic/organic) are specified for galvanizing; alkyds are not.
  • MPI #134: Alkyd primers prohibited on galvanized metal without a conversion coating.

Correct Prep (per SSPC-SP 16):

  1. Solvent wipe (SSPC-SP 1) – remove oils.
  2. Etch: - Chemical: Phosphoric acid wash (e.g., MetalReady, Ospho) per ASTM D5723, rinse, dry. - Mechanical: Brush-off blast (SSPC-SP 7) or 80–100 grit sanding to uniform dull profile.
  3. Prime immediately with waterborne acrylic DTM primer (MPI #134) or epoxy masticnot alkyd.
  4. Topcoat per manufacturer’s recoat window.

Fix Now: Strip failed coating (scrape/pressure wash to sound substrate), etch per above, reprime with acrylic DTM or epoxy, then alkyd topcoat if desired.

Bottom line: Alkyd + bare galvanizing = guaranteed delamination. Use the right primer system.

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